Gen 9 PU
Wo-Chien @ Leftovers
Ability: Tablets of Ruin
Tera Type: Poison
EVs: 252 HP / 252 Def / 4 SpD
Impish Nature
-Leech Seed
-Protect
-Knock Off
-Stun Spore
In the lower tiers, Wo-Chien functions as an all-purpose tank. It doesn't have a reliable healing move, but Leech Seed, Leftovers and Protect can provide fairly consistent healing and chip damage on opponents. Knock Off does decent chip damage and also removes the opponent's item, which is always useful. Stun Spore in the last slot can punish the opponent switching to remove leech seed, and paralysis can gain crucial free turns to set up leech seed or hit a knock off. The given EVs make it amazing at taking both physical and special hits. Poison Tera helps resist Fighting and Bug moves that Wo-Chien is normally weak to, and the psychic types that can hit it super-effectively post-terastallization will have to be careful to avoid a knock off.
Other Options:
Foul Play and Giga Drain are alternative options for the STAB attack move, if using Giga Drain, A Bold nature is preferable.
Taunt can be used in the fourth moveslot for all-purpose utility, in particular preventing opponents to heal off chip damage you deal, or stopping them from boosting up to break through.
Ruination can also be used in the fourth slot to cut the opponent's HP in half, which can help the rest of the team in breaking through.
This is my first analysis, so please tell me if I get anything wrong! All constructive criticism is greatly appreciated.