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I've seen many a Zacian sweep with Blade, but a level 100 Zacian I have in Violet doesn't have Blade, even in its reminders part. How the heck does Zacian learn B.B. if it's not in my goofy dog's moveset?

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Zacian needs to be holding the Rusted Sword and has to know Iron Head. Send it into battle, and it should have Behemoth Blade instead of Iron Head.

Source: Experience playing Gen 8 AG but I tested this in game and it worked.

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It should be obvious but in case you couldn't tell, only Zacian Crowned can use Behemoth Blade.
Okey dokey! I accidentally figured this out but thought it was any steel move, that makes sense. Thanks though!